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Triphosphorus pentanitride
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Triphosphorus pentanitride : ウィキペディア英語版
Triphosphorus pentanitride

Triphosphorus pentanitride is an inorganic compound with the chemical formula P3N5. Containing only phosphorus and nitrogen, this material is classified as a binary nitride. Related compounds are boron nitride and silicon nitride. No applications have been developed for this material, which remains a topic of research. It is a white solid, although samples often appear colored owing to impurities.
== Synthesis ==
Triphosphorus pentanitride can be produced by reactions between various phosphorus(V) and nitrogen compounds (such as ammonia and sodium azide);〔 including a reaction between the elements.
:3 PCl5 + 5 NH3 → P3N5 + 15 HCl
:3 PCl5 + 15 NaN3 → P3N5 + 15 NaCl + 5 N2
Similar methods are used to prepared boron nitride and silicon nitride; however the products are generally impure and amorphous.
Crystalline samples have been produced by the reaction of ammonium chloride and hexachlorocyclotriphosphazene: or phosphorus pentachloride.〔
:(NPCl2)3 + 2 NH4Cl → P3N5 + 8 HCl
:3 PCl5 + 5 NH4Cl → P3N5 + 20 HCl
P3N5 has also been prepared at room temperature, by a reaction between phosphorus trichloride and sodium amide.
:3 PCl3 + 5 NaNH2 → P3N5 + 5 NaCl + 4 HCl + 3 H2

抄文引用元・出典: フリー百科事典『 ウィキペディア(Wikipedia)
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